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11.
针对一类具结构的非对称线性方程组提出了一类子结构预处理子,该预处理子只保留了约束条件的一半项.研究表明,预处理矩阵只有三个离散的特征值.为了避免计算Schur补的逆,还给出了正则化的子结构预处理子,同样对预处理矩阵进行了谱分析.这些结果将Zhou和Niu(Zhou J T,Niu Q.Substructure preconditioners for a class of structuredlinear systems of equations.Math.Comput.Model.,2010,52:1547-1553)的结果推广到非对称结构线性方程组.数值算例验证了提出的子结构预处理子的有效性. 相似文献
12.
Guifang Zeng Yining Liu Chunyan Gu Kai Zhang Yongling An Chuanliang Wei Jinkui Feng Jiangfeng Ni 《物理化学学报》2020,36(5):1905006-0
Lithium-ion batteries (LIBs) are widely used in cellphones, laptops, and electric cars owing to their high energy density and long operational lifetime. However, their further deployment in large-scale energy storage systems is restricted by the uneven distribution of lithium resources (~0.0017% (mass fraction, w) in the Earth's crust). Therefore, alternative energy storage systems composed of abundant elements are of urgent need. Recently, sodium-ion batteries (SIBs) have attracted significant attention and are considered to be a potential alternative for next-generation batteries owing to abundant sodium resources (~2.64% (w) of the Earth's crust), suitable potential (−2.71 V), and low cost. SIBs are similar to LIBs in terms of their physical and electrochemical properties. Previous studies have mainly focused on SIB storage materials, including hard carbon, alloys, and hexacyanoferrate, while the safety of SIBs remains largely unexplored. Similar to LIBs, the current electrolytes used in SIBs are mainly composed of flammable organic carbonate solvents (or ether solvents), sodium salts, and functional additives, which pose possible safety issues. Moreover, the chemical activity of sodium is much higher than that of lithium, leading to a higher risk of fire, thermal runaway, and explosion. To overcome this problem, herein we propose a fluorinated non-flammable electrolyte composed of 0.9 mol∙L−1 NaPF6 (sodium hexafluorophosphate) in an intermixture of di-(2, 2, 2 trifluoroethyl) carbonate (TFEC) and fluoroethylene carbonate (FEC) in a 7 : 3 ratio by volume. Its physical and electrochemical properties were studied by ionic conductivity, direct ignition, cyclic voltammetry, and charge/discharge measurements, demonstrating excellent flame-retarding ability and outstanding compatibility with sodium electrodes. The electrochemical tests showed that the Prussian blue cathode retained a capacity of 84 mAh∙g−1 over 50 cycles in the prepared electrolyte, in contrast to the rapid capacity degradation in a flammable conventional carbonate electrolyte (74 mAh∙g−1 with 57% capacity retention after 50 cycles). To test the practical application of the proposed electrolyte, a hard carbon anode was used and exhibited exceptional performance in this system. The enhancement mechanism was further verified by Fourier transform infrared (FTIR), X-ray diffraction (XRD), and scanning emission microscopy (SEM) investigations. Polycarbonate on the surface of the cathode played an important role for the studied electrolyte system. The polycarbonate may originate from FEC decomposition, which can enhance the ionic conductivity of the solid electrolyte interface (SEI) layer and reduce impedance. Hence, we believe that this proposed electrolyte may provide new opportunities for the design of robust and safe SIBs for next-generation applications. 相似文献
13.
采用水热法制备了系列富锂尖晶石型正极材料Li2+4xMn0.6+2xNi0.6-6xCr0.8O4(x=1/30,1/20,1/15,1/12),通过X射线衍射(XRD)、电感耦合等离子体-原子发射光谱(ICP-AES)、扫描电子显微镜(SEM)、X射线光电子能谱(XPS)、傅里叶变换红外光谱(FTIR)、拉曼光谱、循环伏安(CV)和充放电测试等手段对其结构及电化学性能进行表征.结果表明,所制备的系列材料为富锂型高电压尖晶石结构正极材料,该系列样品在4.7 V左右有放电平台.x=1/15和x=1/12时,样品中的Cr为+3价,没有观测到Cr6+.随着x值的增大,样品中Li离子与过渡金属离子的混排减小,样品的充放电比容量逐渐增大,且2.7 V处的放电平台容量也增加.当x=1/12时,样品具有较好的充放电比容量和倍率特性,首次放电比容量为107.3 mA·h/g,20次循环后容量保持率为84.9%. 相似文献
14.
15.
Liu D. -F. Zhu X. -J. Wang C. -H. Yu J. -J. Fang E. -X. Wang J. -J. 《Laser Physics》2011,21(2):414-418
We report an all normal dispersion low repetition rate high energy passive mode-locked ytterbium-doped fiber laser with output
pulses duration ranging from nanoseconds to picoseconds. The mode-locking mechanism of the laser is based on nonlinear polarization
evolution and strong pulses shaping with a cascade long-period fiber grating bandpass filtering in highly chirped pulses.
The laser generates highly stable pulses duration from 2.62 ns to 315 ps with a maximum pulse energy of 49.5 nJ and 2.5435
MHz repetition rate. 相似文献
16.
C.G. Jin T. Yu Y. Zhao Y. Bo X.M. Wu L.J. Zhuge 《Physica E: Low-dimensional Systems and Nanostructures》2011,43(10):1863-1866
Silicon carbide (SiC) films are prepared by single- and dual-ion beam sputtering deposition at room temperature, respectively. An assisting argon ion beam (ion energy Ei=150 eV) bombards directly the substrate surface to modify the SiC film surface. The thin films are characterized by the Fourier transform infrared spectroscopy (FTIR) and the Raman spectra. With assisting ion beam bombardment, the density of the Si–C bond in the film increases. Meanwhile, the excess carbon or the size of the sp2 bonded clusters and the amorphous Si (a-Si) phase decrease. These results indicate that the composition of the films is mainly Si–C bond. UV-vis transmission shows that the Eopt increases steadily from 1.85 eV for the amorphous SiC (a-SiC) films without bombardment to about 2.29 eV for those with assisting ion beam bombardment. 相似文献
17.
Yang Cao Mei‐Qun Jiang Ying‐Long Zheng 《Numerical Linear Algebra with Applications》2011,18(5):875-895
For large sparse systems of linear equations iterative techniques are attractive. In this paper, we study a splitting method for an important class of symmetric and indefinite system. Theoretical analyses show that this method converges to the unique solution of the system of linear equations for all t>0 (t is the parameter). Moreover, all the eigenvalues of the iteration matrix are real and nonnegative and the spectral radius of the iteration matrix is decreasing with respect to the parameter t. Besides, a preconditioning strategy based on the splitting of the symmetric and indefinite coefficient matrices is proposed. The eigensolution of the preconditioned matrix is described and an upper bound of the degree of the minimal polynomials for the preconditioned matrix is obtained. Numerical experiments of a model Stokes problem and a least‐squares problem with linear constraints presented to illustrate the effectiveness of the method. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
18.
C. Argyropoulos E. Kallos Y. Hao 《Applied Physics A: Materials Science & Processing》2011,103(3):715-719
In this paper, the transient responses of some devices which are based on transformation electromagnetics are studied, such
as invisible cloaks and concentrators, by using the Finite-Difference Time-Domain (FDTD) numerical technique. In particular,
effects of the inherent losses as well as the coating size of the ideal cylindrical cloak on its bandwidth and cloaking performance
are examined. In addition, it is demonstrated that the performance of transformation electromagnetics based devices is affected
by the material parameters in the design, although they may behave nicely under monochromatic plane wave illuminations. The
obtained results are of interest for the future practical implementation of these structures. 相似文献
19.
20.
结构新颖的双阴离子型桥联胺基胍基镱(Ⅲ)配合物{[Me2Si(NPh)2]2Yb[(NiPr)2CN(SiMe3)2]}{Li(THF)2}2是通过二胍基镱氯化物[(SiMe2)2NC(N'Pr)2]2Yb(μ-Cl)2Li(THF)2和桥联胺基锂盐PhLiNSiMe2NLiPh反应制得,该配合物经过了IR、元素分析和X-ray晶体结构的测定.该晶体为单斜晶系,P 21/c空间群,a=14.0001(8),b=17.6808(9),c=24.9565(16)A,B=95.994(3),V=6143.8(6)A3,Dc=1.287g/cm3,Z=4. 相似文献